Debye model

Mathematical model of a solid that treates the vibrations of the atomic lattice as phonons in a box

In thermodynamics and solid-state physics, the Debye model is a method developed by Peter Debye in 1912 to estimate phonon contribution to the specific heat (heat capacity) in a solid. It treats the vibrations of the atomic lattice (heat) as phonons in a box in contrast to the Einstein solid model, which treats the solid as many individual, non-interacting quantum harmonic oscillators.

Nº Q1151031 ★

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Debye model

Mathematical model of a solid that treates the vibrations of the atomic lattice as phonons in a box

In thermodynamics and solid-state physics, the Debye model is a method developed by Peter Debye in 1912 to estimate phonon contribution to the specific heat (heat capacity) in a solid. It treats the vibrations of the atomic lattice (heat) as phonons in a box in contrast to the Einstein solid model, which treats the solid as many individual, non-interacting quantum harmonic oscillators.

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In thermodynamics and solid-state physics, the Debye model is a method developed by Peter Debye in 1912 to estimate phonon contribution to the specific heat (heat capacity) in a solid. It treats the vibrations of the atomic lattice (heat) as phonons in a box in contrast to the Einstein solid model, which treats the solid as many individual, non-interacting quantum harmonic oscillators. The Debye model correctly predicts the low-temperature dependence of the heat capacity of solids, which is proportional to the cube of temperature – the Debye T 3 law. Similarly to the Einstein photoelectron model, it recovers the Dulong–Petit law at high temperatures. Due to simplifying assumptions, its accuracy suffers at intermediate temperatures.

Text: Wikipédia, CC BY-SA 4.0. · Image: Unknown authorUnknown author (Public domain) ·

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