Gadolinium

Gadolinium is a chemical element; it has symbol Gd and atomic number 64. It is a silvery-white metal when oxidation is removed. Gadolinium is a ductile and malleable rare-earth element. It reacts with atmospheric oxygen or moisture slowly to form a black oxide coating. Gadolinium below its Curie point of 20 °C (68 °F) is ferromagnetic, with an attraction to a magnetic field higher than that of nickel. Above this temperature it is the most paramagnetic element. It is found in nature only in an oxidized form. When separated, it usually has impurities of the other rare earths because of their similar chemical properties. Gadolinium was discovered in 1880 by Jean Charles de Marignac, who detected its oxide by using spectroscopy. It is named after the mineral gadolinite, one of the minerals in which gadolinium is found, itself named for the Finnish chemist Johan Gadolin. Pure gadolinium was first isolated by the chemist Félix Trombe in 1935. Gadolinium possesses unusual metallurgical properties, to the extent that as little as 1% of gadolinium can significantly improve the workability and resistance to oxidation at high temperatures of iron, chromium, and related metals. Gadolinium as a metal or a salt absorbs neutrons and is, therefore, used sometimes for shielding in neutron radiography and in nuclear reactors. Like most of the rare earths, gadolinium forms trivalent ions with fluorescent properties, and salts of gadolinium(III) are used as phosphors in various applications. Gadolinium(III) ions in water-soluble salts are highly toxic to mammals. However, chelated gadolinium(III) compounds prevent the gadolinium(III) from being exposed to the organism, and the majority is excreted by healthy kidneys before it can deposit in tissues. Because of its paramagnetic properties, solutions of chelated organic gadolinium complexes are used as intravenously administered gadolinium-based MRI contrast agents in medical magnetic resonance imaging. The...