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Quantum statistical mechanics
Statistical mechanics of quantum-mechanical systems
Quantum statistical mechanics is statistical mechanics applied to quantum mechanical systems. It relies on constructing density matrices that describe quantum systems in thermal equilibrium.
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Its applications include the study of collections of identical particles, which provides a theory that explains phenomena including superconductivity and superfluidity. In quantum mechanics, probabilities for the outcomes of experiments made upon a system are calculated from the quantum state describing that system. Each physical system is associated with a vector space, or more specifically a Hilbert space. The dimension of the Hilbert space may be infinite, as it is for the space of square-integrable functions on a line, which is used to define the quantum physics of a continuous degree of freedom. Alternatively, the Hilbert space may be finite-dimensional, as occurs for spin degrees of freedom. A density operator, the mathematical representation of a quantum state, is a positive semi-definite, self-adjoint operator of trace one acting on the Hilbert space of the system. A density operator that is a rank-1 projection is known as a pure quantum state, and all quantum states that are not pure are designated mixed. Pure states are also known as wavefunctions.
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